Theoretical study of HfF$^+$ for the electron EDM search

dc.creatorPetrov, A. N.
dc.creatorMosyagin, N. S.
dc.creatorTitov, A. V.
dc.date2008-12-14
dc.date.accessioned2026-07-07T12:12:49Z
dc.date.available2026-07-07T12:12:49Z
dc.descriptionWe report ab initio relativistic correlation calculations of potential curves and electric dipole transition moments for ten low-lying electronic states, effective electric field on the electron, hyperfine constants and radiative lifetimes for the $^3Δ_1$ state of cation of the heavy transition metal fluoride HfF$^+$, which it is suggested to be used in experiments to search for the electric dipole moment of the electron. It is obtained that HfF$^+$ has deeply bound $^1Σ^+$ ground state; its dissociation energy is $D_e=6.4$ eV. The $^3Δ_1$ state is obtained as the relatively long-lived, with lifetime equal to about 0.4 s.,first excited state lying about 0.2 eV higher. The calculated effective electric field, $E_{eff}=W_d|Ω|$, acting on an electron in this state is $5.84*10^{24} Hz/{e*cm}$. The obtained hyperfine constants are $A_{\parallel}= -1239$ MHz for the $^{177}$Hf nucleus and $A_{\parallel}= -58.1$ MHz for the $^{19}$F nucleus.
dc.description10 pages, 1 figure
dc.identifierhttps://arxiv.org/abs/0812.2670
dc.identifierhttp://arxiv.org/abs/0812.2670
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/210668
dc.subjectAtomic Physics
dc.subjectChemical Physics
dc.titleTheoretical study of HfF$^+$ for the electron EDM search
dc.typetext

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