Diffusion NMR Methods Applied to Xenon Gas for Materials Study

dc.creatorMair, R. W.
dc.creatorRosen, M. S.
dc.creatorWang, R.
dc.creatorCory, D. G.
dc.creatorWalsworth, R. L.
dc.date2002-11-09
dc.date.accessioned2026-07-07T02:48:07Z
dc.date.available2026-07-07T02:48:07Z
dc.descriptionWe report initial NMR studies of i) xenon gas diffusion in model heterogeneous porous media, and ii) continuous flow laser-polarized xenon gas. Both areas utilize the Pulsed Gradient Spin Echo techniques in the gas-phase, with the aim of obtaining more sophisticated information than just translational self-diffusion coefficients - a brief overview of this area is provided in the introduction. The heterogeneous or multiple-length scale model porous media consisted of random packs of mixed glass beads of two different sizes. We focus on observing the approach of the time-dependent gas diffusion coefficient, D(t), (an indicator of mean squared displacement) to the long-time asymptote, with the aim of understanding the long-length scale structural information that may be derived from a heterogeneous porous system. The Pade approximation is used to interpolate D(t) data between the short and long time limits. Initial studies of continuous flow laser-polarized xenon gas demonstrate velocity-sensitive imaging of much higher flows than can generally be obtained with liquids (20 - 200 mm/s). Gas velocity imaging is, however, found to be limited to a resolution of about 1 mm/s due to the high diffusivity of gases compared to liquids. We also present the first gas-phase NMR scattering, or diffusive-diffraction, data: namely, flow-enhanced structural features in the echo attenuation data from laser-polarized xenon flowing through a 2 mm glass bead pack.
dc.descriptionsingle pdf file including all figures
dc.identifierhttps://arxiv.org/abs/cond-mat/0211179
dc.identifierhttp://arxiv.org/abs/cond-mat/0211179
dc.identifierMagnetic Resonance in Chemistry, 40, S29-S39 (2002)
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/20277
dc.subjectSoft Condensed Matter
dc.subjectMaterials Science
dc.titleDiffusion NMR Methods Applied to Xenon Gas for Materials Study
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