Theoretical Study of the Thermal Decomposition of a Jet Fuel Surrogate
Loading...
Date
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
Description
In a scramjet, the fuel can be used to cool down the engine walls. The thermal decomposition of the jet fuel changes the reacting mixture before its combustion. A numerical study of the pyrolysis of norbornane, a jet fuel surrogate, has been performed. Rate constants of some sensitive reaction channels have been calculated by means of quantum chemical calculations at the CBS-QB3 level of theory. The mechanism has been validated against experimental results obtained in a jet-stirred reactor and important and/or sensitive pathways have been derived.