Overcharging by macroions: above all, an entropy effect
| dc.creator | Lozada-Cassou, Marcelo | |
| dc.creator | Jimenez-Angeles, Felipe | |
| dc.date | 2001-05-15 | |
| dc.date | 2001-05-16 | |
| dc.date.accessioned | 2026-07-07T05:45:48Z | |
| dc.date.available | 2026-07-07T05:45:48Z | |
| dc.description | Model macroion solutions next to a charged wall show interface \textit{true overcharging}, charge reversal and inversion, and layering. Macroion layering is present, even if the wall or the macroparticle are \textit{uncharged} or if the wall and macroions are like-charged. An effective long-range attractive force between the adsorbed macroions is implied. The results are obtained through an integral equation theory and a new extended Poisson-Boltzmann theory, and are in accordance with experiments on confined macroions and polymer layering. | |
| dc.description | 4 pages, 5 figures | |
| dc.identifier | https://arxiv.org/abs/physics/0105043 | |
| dc.identifier | http://arxiv.org/abs/physics/0105043 | |
| dc.identifier.uri | http://salesiana.dossiersoluciones.com/handle/123456789/84123 | |
| dc.subject | Chemical Physics | |
| dc.title | Overcharging by macroions: above all, an entropy effect | |
| dc.type | text |