Complex coacervation: A field theoretic simulation study of polyelectrolyte complexation

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dc.creatorLee, Jonghoon
dc.creatorPopov, Yuri O.
dc.creatorFredrickson, Glenn H.
dc.date2008-03-27
dc.date.accessioned2026-07-07T09:44:17Z
dc.date.available2026-07-07T09:44:17Z
dc.descriptionUsing the complex Langevin sampling strategy, field theoretic simulations are performed to study the equilibrium phase behavior and structure of symmetric polycation-polyanion mixtures without salt in good solvents. Static structure factors for the segment density and charge density are calculated and used to study the role of fluctuations in the electrostatic and chemical potential fields beyond the random phase approximation. We specifically focus on the role of charge density and molecular weight on the structure and complexation behavior of polycation-polyanion solutions. A demixing phase transition to form a ``complex coacervate'' is observed in strongly charged systems, and the corresponding spinodal and binodal boundaries of the phase diagram are investigated.
dc.identifierhttps://arxiv.org/abs/0803.3994
dc.identifierhttp://arxiv.org/abs/0803.3994
dc.identifierJ. Chem. Phys. 128, 224908 (2008)
dc.identifierdoi:10.1063/1.2936834
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/162817
dc.subjectSoft Condensed Matter
dc.subjectStatistical Mechanics
dc.titleComplex coacervation: A field theoretic simulation study of polyelectrolyte complexation
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