Slip boundary conditions for shear flow of polymer melts past atomically flat surfaces

dc.creatorNiavarani, Anoosheh
dc.creatorPriezjev, Nikolai V.
dc.date2007-11-01
dc.date2008-02-07
dc.date.accessioned2026-07-07T09:33:21Z
dc.date.available2026-07-07T09:33:21Z
dc.descriptionMolecular dynamics simulations are carried out to investigate the dynamic behavior of the slip length in thin polymer films confined between atomically smooth thermal surfaces. For weak wall-fluid interactions, the shear rate dependence of the slip length acquires a distinct local minimum followed by a rapid growth at higher shear rates. With increasing fluid density, the position of the local minimum is shifted to lower shear rates. We found that the ratio of the shear viscosity to the slip length, which defines the friction coefficient at the liquid/solid interface, undergoes a transition from a nearly constant value to the power law decay as a function of the slip velocity. In a wide range of shear rates and fluid densities, the friction coefficient is determined by the product of the value of surface induced peak in the structure factor and the contact density of the first fluid layer near the solid wall.
dc.description27 pages, 11 figures
dc.identifierhttps://arxiv.org/abs/0711.0178
dc.identifierhttp://arxiv.org/abs/0711.0178
dc.identifierPhys. Rev. E 77, 041606 (2008)
dc.identifierdoi:10.1103/PhysRevE.77.041606
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/159102
dc.subjectSoft Condensed Matter
dc.subjectMaterials Science
dc.subjectFluid Dynamics
dc.titleSlip boundary conditions for shear flow of polymer melts past atomically flat surfaces
dc.typetext

Files

Collections