A Lean Methane Prelixed Laminar Flame Doped witg Components of Diesel Fuel. Part I: n)Butylbenzene

dc.creatorPousse, Emir
dc.creatorGlaude, Pierre-Alexandre
dc.creatorFournet, René
dc.creatorBattin-Leclerc, Frédérique
dc.date2009-03-28
dc.date.accessioned2026-07-07T12:57:38Z
dc.date.available2026-07-07T12:57:38Z
dc.descriptionTo better understand the chemistry involved during the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with n-butylbenzene has been investigated. The inlet gases contained 7.1% (molar) of methane, 36.8% of oxygen and 0.96% of n-butylbenzene corresponding to an equivalence ratio of 0.74 and a ratio C10H14 / CH4 of 13.5%. The flame has been stabilized on a burner at a pressure of 6.7 kPa using argon as diluent, with a gas velocity at the burner of 49.2 cm/s at 333 K. Quantified species included the usual methane C0-C2 combustion products, but also 16 C3-C5 hydrocarbons, 7 C1-C3 oxygenated compounds, as well as 20 aromatic products, namely benzene, toluene, phenylacetylene, styrene, ethylbenzene, xylenes, allylbenzene, propylbenzene, cumene, methylstyrenes, butenylbenzenes, indene, indane, naphthalene, phenol, benzaldehyde, anisole, benzylalcohol, benzofuran, and isomers of C10H10 (1-methylindene, dihydronaphtalene, butadienylbenzene). A new mechanism for the oxidation of n-butylbenzene is proposed whose predictions are in satisfactory agreement with measured species profiles in flames and flow reactor experiments. The main reaction pathways of consumption of n butylbenzene have been derived from flow rate analyses.
dc.identifierhttps://arxiv.org/abs/0903.4948
dc.identifierhttp://arxiv.org/abs/0903.4948
dc.identifierCombustion and Flame 156 (2009) 954-974
dc.identifierdoi:10.1016/j.combustflame.2008.09.012
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/225001
dc.subjectChemical Physics
dc.titleA Lean Methane Prelixed Laminar Flame Doped witg Components of Diesel Fuel. Part I: n)Butylbenzene
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