Effects of charge-dependent vibrational frequencies and anharmonicities in transport through molecules

dc.creatorKoch, Jens
dc.creatorvon Oppen, Felix
dc.date2005-07-30
dc.date.accessioned2026-07-07T03:06:10Z
dc.date.available2026-07-07T03:06:10Z
dc.descriptionAs a step towards a more realistic modeling of vibrations in single-molecule devices, we investigate the effects of charge-dependent vibrational frequencies and anharmonic potentials on electronic transport. For weak phonon relaxation, we find that in both cases vibrational steps split into a multitude of substeps. This effectively leads to a bias-dependent broadening of vibrational features in current-voltage and conductance characteristics, which provides a fingerprint of nonequilibrium vibrations whenever other broadening mechanisms are secondary. In the case of an asymmetric molecule-lead coupling, we observe that frequency differences can also cause negative differential conductance.
dc.description4+ pages, 3 figures; accepted for publication in Phys. Rev. B. (Brief Reports)
dc.identifierhttps://arxiv.org/abs/cond-mat/0508011
dc.identifierhttp://arxiv.org/abs/cond-mat/0508011
dc.identifierPhys. Rev. B 72, 113308 (2005)
dc.identifierdoi:10.1103/PhysRevB.72.113308
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/26713
dc.subjectMesoscale and Nanoscale Physics
dc.titleEffects of charge-dependent vibrational frequencies and anharmonicities in transport through molecules
dc.typetext

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