The Transition State in a Noisy Environment

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dc.creatorBartsch, Thomas
dc.creatorHernandez, Rigoberto
dc.creatorUzer, T.
dc.date2005-06-09
dc.date.accessioned2026-07-07T06:22:19Z
dc.date.available2026-07-07T06:22:19Z
dc.descriptionTransition State Theory overestimates reaction rates in solution because conventional dividing surfaces between reagents and products are crossed many times by the same reactive trajectory. We describe a recipe for constructing a time-dependent dividing surface free of such recrossings in the presence of noise. The no-recrossing limit of Transition State Theory thus becomes generally available for the description of reactions in a fluctuating environment.
dc.identifierhttps://arxiv.org/abs/cond-mat/0506231
dc.identifierhttp://arxiv.org/abs/cond-mat/0506231
dc.identifierPhys. Rev. Lett. 95 (2005) 058301
dc.identifierdoi:10.1103/PhysRevLett.95.058301
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/95874
dc.subjectStatistical Mechanics
dc.titleThe Transition State in a Noisy Environment
dc.typetext

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