K S Krishnan and the early experimental evidences for the Jahn-Teller Theorem

dc.creatorBaskaran, G.
dc.date1999-06-13
dc.date.accessioned2026-07-07T03:13:41Z
dc.date.available2026-07-07T03:13:41Z
dc.descriptionJahn-Teller theorem, proposed in 1937, predicts a distortional instability for a molecule that has symmetry based degenerate electronic states. In 1939 Krishnan emphasized the importance of this theorem for the arrangement of water molecules around the transition metal or rare earth ions in aqueous solutions and hydrated saltes, in a short and interesting paper published in Nature by pointing out atleast four existing experimental results in support of the theorem. This paper of Krishnan has remained essentially unknown to the practitioners of Jahn-Teller effect, eventhough it pointed to the best experimental results that were available, in the 30's and 40's, in support of Jahn-Teller theorem. Some of the modern day experiments are also in conformity with some specific suggestions of Krishnan.
dc.description3 pages, LaTex version
dc.identifierhttps://arxiv.org/abs/cond-mat/9906184
dc.identifierhttp://arxiv.org/abs/cond-mat/9906184
dc.identifierCurrent Science (Bangalore) vol.75, pp.1254-1258, 1998 (K S Krishnan Birth Centenary Section)
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/29390
dc.subjectCondensed Matter
dc.titleK S Krishnan and the early experimental evidences for the Jahn-Teller Theorem
dc.typetext

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