Thermodynamic modeling of the Hf-Si-O system

dc.creatorShin, Dongwon
dc.creatorArróyave, Raymundo
dc.creatorLiu, Zi-Kui
dc.date2007-08-30
dc.date.accessioned2026-07-07T08:26:50Z
dc.date.available2026-07-07T08:26:50Z
dc.descriptionThe Hf-O system has been modeled by combining existing experimental data and first-principles calculations results through the CALPHAD approach. Special quasirandom structures of $α$ and $β$ hafnium were generated to calculate the mixing behavior of oxygen and vacancies. For the total energy of oxygen, vibrational, rotational and translational degrees of freedom were considered. The Hf-O system was combined with previously modeled Hf-Si and Si-O systems, and the ternary compound in the Hf-Si-O system, HfSiO$_4$ has been introduced to calculate the stability diagrams pertinent to the thin film processing.
dc.description13 pages, 11 figures
dc.identifierhttps://arxiv.org/abs/0708.4239
dc.identifierhttp://arxiv.org/abs/0708.4239
dc.identifierCALPHAD, 30(4), 375-386 (2006)
dc.identifierdoi:10.1016/j.calphad.2006.08.006
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/137078
dc.subjectMaterials Science
dc.titleThermodynamic modeling of the Hf-Si-O system
dc.typetext

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