Anomalous pH-gradient in Ampholyte Solution

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dc.creatorSakharova, L. V.
dc.creatorVladimirov, V. A.
dc.creatorZhukov, M. Yu.
dc.date2009-02-21
dc.date.accessioned2026-07-07T12:45:29Z
dc.date.available2026-07-07T12:45:29Z
dc.descriptionA mathematical model describing a steady pH-gradient in the solution of ampholytes in water has been studied with the use of analytical, asymptotic, and numerical methods. We show that at the large values of an electric current a concentration distribution takes the form of a piecewise constant function that is drastically different from a classical Gaussian form. The correspondent pH-gradient takes a stepwise form, instead of being a linear function. A discovered anomalous pH-gradient can crucially affect the understanding of an isoelectric focusing process.
dc.description5 pages, 2 figures
dc.identifierhttps://arxiv.org/abs/0902.3758
dc.identifierhttp://arxiv.org/abs/0902.3758
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/221100
dc.subjectChemical Physics
dc.titleAnomalous pH-gradient in Ampholyte Solution
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