On a mechanism low-pressure insertion of chain molecules into crystalline matrices
| dc.creator | Vakarin, E. V. | |
| dc.creator | Badiali, J. P. | |
| dc.date | 2006-05-29 | |
| dc.date | 2006-05-30 | |
| dc.date.accessioned | 2026-07-07T07:09:15Z | |
| dc.date.available | 2026-07-07T07:09:15Z | |
| dc.description | A microscopic mechanism of low-pressure insertion and separation of chain-like molecules in host matrices is proposed. It is shown that the intramolecular correlations combined to appropriate host activities are responsible for a low-pressure condensation of chain molecules. This allows recover a fine structure of the isotherms and to explain recent experiments on the insertion of $C_2H_2$ and $CO_2$ guest species. We argue that the mechanism should be dominant in low-dimensional host geometries, where the entropic effects are strongly suppressed and the major factors are the chain connectivity and packing. | |
| dc.identifier | https://arxiv.org/abs/cond-mat/0605704 | |
| dc.identifier | http://arxiv.org/abs/cond-mat/0605704 | |
| dc.identifier.uri | http://salesiana.dossiersoluciones.com/handle/123456789/110995 | |
| dc.subject | Statistical Mechanics | |
| dc.title | On a mechanism low-pressure insertion of chain molecules into crystalline matrices | |
| dc.type | text |