Capillary bridging and long-range attractive forces in a mean-field approach

dc.creatorAndrienko, D.
dc.creatorPatricio, P.
dc.creatorVinogradova, O. I.
dc.date2004-06-16
dc.date.accessioned2026-07-07T02:58:39Z
dc.date.available2026-07-07T02:58:39Z
dc.descriptionWhen a mixture is confined, one of the phases can condense out. This condensate, which is otherwise metastable in the bulk, is stabilized by the presence of surfaces. In a sphere-plane geometry, routinely used in atomic force microscope (AFM) and surface force apparatus (SFA), it can form a bridge connecting the surfaces. The pressure drop in the bridge gives rise to additional long-range attractive forces between them. Minimizing the free energy of a binary mixture we obtain the force-distance curves as well as the structural phase diagram of the configuration with the bridge. Numerical results predict a discontinuous transition between the states with and without the bridge and linear force-distance curves with hysteresis. We also show that similar phenomenon can be observed in a number of different systems, e.g. liquid crystals and polymer mixtures.
dc.identifierhttps://arxiv.org/abs/cond-mat/0406372
dc.identifierhttp://arxiv.org/abs/cond-mat/0406372
dc.identifierJ. Chem. Phys., 121, 4414, 2004
dc.identifierdoi:10.1063/1.1778154
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/24187
dc.subjectSoft Condensed Matter
dc.titleCapillary bridging and long-range attractive forces in a mean-field approach
dc.typetext

Files

Collections