Modeling Study of the Low-Temperature Oxidation of Large Methyl Esters

Biet, Joffrey; Warth, Valérie; Herbinet, Olivier; Glaude, Pierre-Alexandre; Battin-Leclerc, Frédérique

Modeling Study of the Low-Temperature Oxidation of Large Methyl Esters

Authors

Biet, Joffrey

Warth, Valérie

Herbinet, Olivier

Glaude, Pierre-Alexandre

Battin-Leclerc, Frédérique

Description

This study focuses on the automatic generation by the software EXGAS of kinetic models for the oxidation of large methyl esters using a single set of kinetic parameters. The obtained models allow to well reproduce the oxidation of n-decane / methyl palmitate mixture in a jet-stirred reactor. This paper also presents the construction and a comparison of models for methyl esters from C7 up to C17 in terms f conversion in a jet-stirred reactor and of ignition delay time in a shock tube. This comparison study showed that methyl esters larger than methyl octanoate behave similarly and have very close reactivities.
European Combustion Meeting 2009, Vienne : Autriche (2009)