Virial coefficients and equations of state for mixtures of hard discs, hard spheres and hard hyperspheres

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dc.creatorSantos, A.
dc.creatorYuste, S. B.
dc.creatorde Haro, M. López
dc.date2001-01-08
dc.date2001-05-09
dc.date.accessioned2026-07-07T02:39:58Z
dc.date.available2026-07-07T02:39:58Z
dc.descriptionThe composition-independent virial coefficients of a $d$-dimensional binary mixture of (additive) hard hyperspheres following from a recent proposal for the equation of state of the mixture [Santos, A., Yuste, S. B., and López de Haro, M., 1999, Molec. Phys., 96, 1] are examined. Good agreement between theoretical estimates and available exact or numerical results is found for $d=2$, 3, 4 and 5, except for mixtures whose components are very disparate in size. A slight modification that remedies this deficiency is introduced and the resummation of the associated virial series is carried out, leading to a new proposal for the equation of state. The case of binary hard-sphere mixtures ($d=3$) is analyzed in some detail.
dc.description22 pages, including 12 figures
dc.identifierhttps://arxiv.org/abs/cond-mat/0101098
dc.identifierhttp://arxiv.org/abs/cond-mat/0101098
dc.identifierMol. Phys. 99, 1959-1972 (2001)
dc.identifierdoi:10.1080/00268970110063890
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/17230
dc.subjectStatistical Mechanics
dc.subjectChemical Physics
dc.titleVirial coefficients and equations of state for mixtures of hard discs, hard spheres and hard hyperspheres
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