The Reasons of Line Broadening of Lattice Oscillations in Spectrum Small Frequencies of P-Chloronitrobenzene

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Raman spectroscopies are carried out by the Method polarizable examinations of the lattice oscillations of p-chloronitrobenzene at temperature 293 K. The led matching of spectrums of p-chloronitrobenzene with p-bromochlorobenzene and p-dibromobenzene has shown that the significant line broadening in p-chloronitrobenzene is caused not only clutter in allocation of molecules concerning parasubstitution benzol. It is necessary to consider also and clutter in rotational displacements of the nitro of group concerning a plane of a molecule. Calculations of frequency spectra were led on a method the Dyne.
4 pages, PDF PACS: 78.30. E; 61.72. J; 61.66. H; 78.30. J

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