Metal-insulator transition in PF6 doped polypyrrole: interchain charge transfer versus electronic correlation
| dc.creator | Martens, H. C. F. | |
| dc.creator | Brom, H. B. | |
| dc.creator | Menon, R. | |
| dc.date | 2001-01-12 | |
| dc.date.accessioned | 2026-07-07T02:40:02Z | |
| dc.date.available | 2026-07-07T02:40:02Z | |
| dc.description | We performed dielectric spectroscopy on polypyrrole near the metal-insulator transition (MIT) down to 2 K. We evaluate the dependence of the plasma frequency and the scattering time (t) on the distance to the MIT, characterized by the Fermi-level relative to the band-edge of extended states, E_F-E_c. Especially the strong decrease of t with increasing E_F-E_c is in conflict with the usually applied models for the MIT. Although morphology and disorder are important, the MIT is Mott-Hubbard-like being dominated by the competition of interchain charge transfer and electronic correlation. | |
| dc.description | 4 pages including 4 figures | |
| dc.identifier | https://arxiv.org/abs/cond-mat/0101178 | |
| dc.identifier | http://arxiv.org/abs/cond-mat/0101178 | |
| dc.identifier.uri | http://salesiana.dossiersoluciones.com/handle/123456789/17249 | |
| dc.subject | Soft Condensed Matter | |
| dc.subject | Materials Science | |
| dc.title | Metal-insulator transition in PF6 doped polypyrrole: interchain charge transfer versus electronic correlation | |
| dc.type | text |