Ionization of the Xenon Fluorides
| dc.creator | Buth, Christian | |
| dc.creator | Santra, Robin | |
| dc.creator | Cederbaum, Lorenz S. | |
| dc.date | 2003-06-15 | |
| dc.date | 2003-12-06 | |
| dc.date.accessioned | 2026-07-07T05:49:28Z | |
| dc.date.available | 2026-07-07T05:49:28Z | |
| dc.description | The noble-gas atom xenon can bind fluorine atoms and form several stable compounds. We study the electronic structure of the xenon fluorides (XeFn, n = 2,4,6) by calculating their ionization spectra using a Green's function method, which allows to treat many-body effects at a high level. Our focus is on the valence region and on the Xe 4d core hole. We observe a sensitive dependence of the spectra on the number of fluorine ligands. Systematic line shifts are uncovered and explained. In the Xe 5s and F 2s inner-valence regimes, from XeF2 to XeF6, the usefulness of the one-particle picture of ionization is found to become progressively worse. Moreover, adding the electronegative fluorine ligands seems to enhance--not suppress--the Auger decay of a Xe 4d core hole. | |
| dc.description | 10 pages, 2 figures, 4 tables, RevTeX4, corrected typos | |
| dc.identifier | https://arxiv.org/abs/physics/0306123 | |
| dc.identifier | http://arxiv.org/abs/physics/0306123 | |
| dc.identifier | J. Chem. Phys. 119, 7763--7771 (2003) | |
| dc.identifier | doi:10.1063/1.1609975 | |
| dc.identifier.uri | http://salesiana.dossiersoluciones.com/handle/123456789/85402 | |
| dc.subject | Chemical Physics | |
| dc.title | Ionization of the Xenon Fluorides | |
| dc.type | text |