Intermediate Phase IV in Structural Phase Transitions of TlCoCl$_3$

dc.creatorNishiwaki, Yoichi
dc.creatorOosawa, Akira
dc.creatorKato, Tetsuya
dc.creatorHasegawa, Takumi
dc.creatorKuroe, Haruhiko
dc.creatorKakurai, Kazuhisa
dc.date2008-08-14
dc.date2008-08-15
dc.date.accessioned2026-07-07T09:56:38Z
dc.date.available2026-07-07T09:56:38Z
dc.descriptionThe structural changes of TlCoCl$_3$ around phase IV (68 K $<T<$ 75 K) were studied by single-crystal neutron diffraction measurement. The present investigation revealed that a small but definite Bragg peak at (${1/6} {1/6} 2$) appeared only in phase IV. A precursor phenomenon of the phase V ($T<$ 68 K) structure in the phase IV temperatures was also identified as the coexistence of a slightly broadened (${1/4} {1/4} 2$) Bragg peak. We confirmed that intermediate phase IV is a stable, nontransient, single phase with $2\sqrt{3}a\times 2\sqrt{3}a\times c$ unit cells. A possible sequence of structural phase transitions was proposed.
dc.description4 pages, 3 figures
dc.identifierhttps://arxiv.org/abs/0808.1954
dc.identifierhttp://arxiv.org/abs/0808.1954
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/167048
dc.subjectMaterials Science
dc.titleIntermediate Phase IV in Structural Phase Transitions of TlCoCl$_3$
dc.typetext

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