Heat capacity in bits

dc.creatorFraundorf, P.
dc.date1997-11-10
dc.date1999-10-01
dc.date.accessioned2026-07-07T03:09:25Z
dc.date.available2026-07-07T03:09:25Z
dc.descriptionInformation theory this century has clarified the 19th century work of Gibbs, and has shown that natural units for temperature kT, defined via 1/T=dS/dE, are energy per nat of information uncertainty. This means that (for any system) the total thermal energy E over kT is the log-log derivative of multiplicity with respect to energy, and (for all b) the number of base-b units of information lost about the state of the system per b-fold increase in the amount of thermal energy therein. For ``un-inverted'' (T>0) systems, E/kT is also a temperature-averaged heat capacity, equaling ``degrees-freedom over two'' for the quadratic case. In similar units the work-free differential heat capacity C_v/k is a ``local version'' of this log-log derivative, equal to bits of uncertainty gained per 2-fold increase in temperature. This makes C_v/k (unlike E/kT) independent of the energy zero, explaining in statistical terms its usefulness for detecting both phase changes and quadratic modes.
dc.description7 pages (3 figs, 16 refs) RevTeX; clarify, new plots; comments http://www.umsl.edu/~fraundor/cm971174.html
dc.identifierhttps://arxiv.org/abs/cond-mat/9711074
dc.identifierhttp://arxiv.org/abs/cond-mat/9711074
dc.identifierAmer. J. Phys. 71 (11) 1142-1151 (November 2003)
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/27875
dc.subjectStatistical Mechanics
dc.subjectChemical Physics
dc.subjectPhysics Education
dc.titleHeat capacity in bits
dc.typetext

Files

Collections