Magnetocaloric effect in hexacyanochromate Prussian blue analogs

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dc.creatorManuel, Esperanca
dc.creatorEvangelisti, Marco
dc.creatorAffronte, Marco
dc.creatorOkubo, Masashi
dc.creatorTrain, Cyrille
dc.creatorVerdaguer, Michel
dc.date2006-02-24
dc.date.accessioned2026-07-07T07:01:57Z
dc.date.available2026-07-07T07:01:57Z
dc.descriptionWe report on the magnetocaloric properties of two molecule-based hexacyanochromate Prussian blue analogs, nominally CsNi[Cr(CN)_6](H_2O) and Cr_3[Cr(CN)_6]_2x12(H_2O). The former orders ferromagnetically below Tc=90 K, whereas the latter is a ferrimagnet below Tc=230 K. For both, we find significantly large magnetic entropy changes DSm associated to the magnetic phase transitions. Notably, our studies represent the first attempt to look at molecule-based materials in terms of the magnetocaloric effect for temperatures well above the liquid helium range.
dc.description4 pages, 6 figures
dc.identifierhttps://arxiv.org/abs/cond-mat/0602589
dc.identifierhttp://arxiv.org/abs/cond-mat/0602589
dc.identifierPhys. Rev. B 73, 172406 (2006)
dc.identifierdoi:10.1103/PhysRevB.73.172406
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/108438
dc.subjectMaterials Science
dc.titleMagnetocaloric effect in hexacyanochromate Prussian blue analogs
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