Gas Bubbles and Gas Pancakes at Liquid/Solid Interface: A Continuum Theory Incorporated with Molecular Interactions

Simple item page
dc.creatorLi, Zhaoxia
dc.creatorZhang, Xuehua
dc.creatorZhang, Lijuan
dc.creatorZeng, Xiaocheng
dc.creatorHu, Jun
dc.creatorFang, Haiping
dc.date2006-08-04
dc.date2007-10-27
dc.date.accessioned2026-07-07T08:38:41Z
dc.date.available2026-07-07T08:38:41Z
dc.descriptionThe states of gas accumulated at the liquid-solid interface are analyzed based on the continuum theory where the Hamaker constant is used to describe the long-range interaction at the microscopic scale. The Hamaker constant is always negative, whereas the gas spreading coefficient can be either sign. Despite the complexity of gas, including that the density profile may not be uniform due to absorption on both solid and liquid surfaces, we predict three possible gas states at the liquid-solid interface, i.e. complete wetting, partial wetting and pseudopartial wetting. These possible gas states correspond respectively to a gas pancake (or film) surrounded by a wet solid, a gas bubble with a finite contact angle, and a gas bubble(s) coexisting with a gas pancake. Typical thickness of the gas pancakes is at the nanoscale within the force range of the long-range interaction, whereas the radius of the gas bubbles can be large. The state of gas bubble(s) coexisting with a gas film is predicted theoretically for the first time. Our theoretical results can contribute to the development of a unified picture of gas nucleation at the liquid-solid interface.
dc.identifierhttps://arxiv.org/abs/cond-mat/0608104
dc.identifierhttp://arxiv.org/abs/cond-mat/0608104
dc.identifierThe paper was published in J. Phys. Chem. B 111, 9325-9329 (2007) with a title of 'Analysis of the Gas states at Liquid/Solid Interface based on interactions at the microscopic level'
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/140817
dc.subjectSoft Condensed Matter
dc.titleGas Bubbles and Gas Pancakes at Liquid/Solid Interface: A Continuum Theory Incorporated with Molecular Interactions
dc.typetext

Files

Collections

arXiv