H_2 Dissociative Adsorption at the Armchair Edges of Graphite

dc.creatorDino, Wilson Agerico
dc.creatorMiura, Yoshio
dc.creatorNakanishi, Hiroshi
dc.creatorKasai, Hideaki
dc.creatorSugimoto, Tsuyoshi
dc.creatorKondo, Takuya
dc.date2004-08-05
dc.date.accessioned2026-07-07T02:59:35Z
dc.date.available2026-07-07T02:59:35Z
dc.descriptionWe investigate and discuss how hydrogen behaves at the edges of a graphite sheet, in particular the armchair edge. Our density functional theory-based calculations results show that, in contrast to the zigzag edge [cf., e-J. Surf. Sci. Nanotech. 2 (2004) 77], regardless of orientation, there is an activation barrier hindering H_2 dissociation at the armchair edges. And once they do get dissociatively adsorbed at the armchair edges, we find that it would be extremely hard to desorb the H from their adsorption sites at the armchair edges. Furthermore, we also found that, consistent with our earlier conclusions [cf., J. Phys. Soc. Jpn. 72 (2003) 1867], it is unlikely that we would find a whole H_2 in between plain graphite sheets.
dc.description4 pages, 5 figures, preprint
dc.identifierhttps://arxiv.org/abs/cond-mat/0408108
dc.identifierhttp://arxiv.org/abs/cond-mat/0408108
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/24570
dc.subjectMaterials Science
dc.subjectOther Condensed Matter
dc.titleH_2 Dissociative Adsorption at the Armchair Edges of Graphite
dc.typetext

Files

Collections