Fluctuation-driven heterogeneous chemical processes

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We explore a new framework for describing the kinetics of a heterogeneous chemical reaction where two particles of the same chemical species form a reaction product of another chemical species on the surface of a seed particle. Traditional treatments neglect the effect of statistical fluctuations in populations. We employ techniques in a manner analogous to the treatment of quantum systems to develop a stochastic description of processes beyond the mean field approximation.
23 pages, 19 figures

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Other Condensed Matter

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http://salesiana.dossiersoluciones.com/handle/123456789/141063

Consulte el texto completo en el siguiente enlace:

https://arxiv.org/abs/0710.5540
 http://arxiv.org/abs/0710.5540

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arXiv