3D ordered composites of nanopolyacetylene: Mechanism of self-organization and properties
| dc.creator | Kobryanskii, Valerii M. | |
| dc.date | 2006-07-28 | |
| dc.date | 2007-04-24 | |
| dc.date.accessioned | 2026-07-07T07:57:52Z | |
| dc.date.available | 2026-07-07T07:57:52Z | |
| dc.description | In 1987-89 were synthesized soluble nano-composites of polyacetylene (NPA) with an abnormally high intensity of Raman scattering and high stability under laser radiation. Here we demonstrate that the key pre-condition to the outstanding characteristics of NPA is the vibrational and rotational mobility of nano-particles, provided by plasticized layers of water on their surface. The results afford a connection between optical properties of NPA and the three-dimensional coherent order arising from self-organization of nanoparticles at synthesis and during film formation. The driving force behind self-organization is the abnormal high vibrational hyper-polarizability of macromolecules leading to coherent dispersive interactions. The principles of synthesis employed can further be used to create 3-D coherently ordered photon crystals and meta-materials. | |
| dc.description | 14 pages, 3 figures | |
| dc.identifier | https://arxiv.org/abs/cond-mat/0607780 | |
| dc.identifier | http://arxiv.org/abs/cond-mat/0607780 | |
| dc.identifier.uri | http://salesiana.dossiersoluciones.com/handle/123456789/127807 | |
| dc.subject | Materials Science | |
| dc.title | 3D ordered composites of nanopolyacetylene: Mechanism of self-organization and properties | |
| dc.type | text |