Direct measurement of polaron binding energy in AMnO$_{3}$ as a function of the A site ionic size by photoinduced IR absorption
| dc.creator | Mertelj, T. | |
| dc.creator | Hrovat, M. | |
| dc.creator | Kuščer, D. | |
| dc.creator | Mihailovic, D. | |
| dc.date | 2000-05-04 | |
| dc.date.accessioned | 2026-07-07T02:37:33Z | |
| dc.date.available | 2026-07-07T02:37:33Z | |
| dc.description | Photoinduced IR absorption was measured in undoped (LaMn)_{1-δ}O_{3} and (NdMn)_{1-δ}O_{3}. We observe broadening and a ~44% increase of the midinfrared anti-Jahn-Teller polaron peak energy when La^{3+} is replaced with smaller Nd^{3+}. The absence of any concurent large frequency shifts of the observed PI phonon bleaching peaks and the Brillouin-zone-center internal perovskite phonon modes measured by Raman and infrared spectroscopy indicate that the polaron peak energy shift is mainly a consequence of an increase of the electron phonon coupling constant with decreasing ionic radius <r_{A}> on the perovskite A site. This indicates that the dynamical lattice effects strongly contribute to the electronic band narrowing with decreasing <r_{A}> in doped giant magnetoresistance manganites. | |
| dc.description | RevTex, 2 postscript figures | |
| dc.identifier | https://arxiv.org/abs/cond-mat/0005088 | |
| dc.identifier | http://arxiv.org/abs/cond-mat/0005088 | |
| dc.identifier.uri | http://salesiana.dossiersoluciones.com/handle/123456789/16332 | |
| dc.subject | Condensed Matter | |
| dc.title | Direct measurement of polaron binding energy in AMnO$_{3}$ as a function of the A site ionic size by photoinduced IR absorption | |
| dc.type | text |