Model for the free-volume distributions of equilibrium fluids

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dc.creatorKrekelberg, William P.
dc.creatorGanesan, Venkat
dc.creatorTruskett, Thomas M.
dc.date2006-06-01
dc.date.accessioned2026-07-07T07:12:22Z
dc.date.available2026-07-07T07:12:22Z
dc.descriptionWe introduce and test via molecular simulation a simple model for predicting the manner in which interparticle interactions and thermodynamic conditions impact the single-particle free-volume distributions of equilibrium fluids. The model suggests a scaling relationship for the density-dependent behavior of the hard-sphere system. It also predicts how the second virial coefficients of fluids with short-range attractions affect their free-volume distributions.
dc.description7 pages, 5 figures
dc.identifierhttps://arxiv.org/abs/cond-mat/0606044
dc.identifierhttp://arxiv.org/abs/cond-mat/0606044
dc.identifierJ. Chem. Phys. 124, 214502 (2006)
dc.identifierdoi:10.1063/1.2202354
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/112058
dc.subjectSoft Condensed Matter
dc.titleModel for the free-volume distributions of equilibrium fluids
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