Thermodynamic theory of kinetic overshoots

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dc.creatorGorban, A. N.
dc.creatorYablonsky, G. S.
dc.date2005-05-19
dc.date.accessioned2026-07-07T05:54:53Z
dc.date.available2026-07-07T05:54:53Z
dc.descriptionEverything that is not prohibited is permissible. So, what is prohibited in the course of chemical reactions, heat transfer and other dissipative processes? Is it possible to "overshoot" the equilibrium, and if yes, then how far? Thermodynamically allowed and prohibited trajectories of processes are discussed by the example of effects of equilibrium encircling. The complete theory of thermodynamically accessible states is presented. The space of all thermodynamically admissible paths is presented by projection on the "thermodynamic tree", that is the tree of the related thermodynamic potential (entropy, free energy, free enthalpy) in the balance polyhedron. The stationary states and limit points for open systems are localized too.
dc.descriptionIMACS2005 extended abstract
dc.identifierhttps://arxiv.org/abs/physics/0505135
dc.identifierhttp://arxiv.org/abs/physics/0505135
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/87121
dc.subjectChemical Physics
dc.subjectGeneral Physics
dc.titleThermodynamic theory of kinetic overshoots
dc.typetext

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