Magnetic properties and the electronic structure of LiCoO_2

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dc.creatorRadwanski, R. J.
dc.creatorRopka, Z.
dc.date2006-10-23
dc.date.accessioned2026-07-07T10:08:17Z
dc.date.available2026-07-07T10:08:17Z
dc.descriptionWe have described properties of LiCoO_2 within the Quantum Atomistic Solid State (QUASST) theory taking into account very strong electron correlations, predominantly of the intra-atomic origin, spin-orbit coupling and the detailed local crystallographic surroundings and its symmetry. Properties of LiCoO_2 are consistently explained together with NaCoO_2 and LaCoO_3 - in all of these compounds the Co^3+ ions occur in the low-spin state. This low-spin state is the effect of the relatively strong crystal-field interactions (B_4^z = +320 K <=> 10Dq = 3.3 eV) and is a manifestation of the very large orbital moment of the Co^3+ ion.
dc.description4 pages, 3 figures embedded
dc.identifierhttps://arxiv.org/abs/cond-mat/0610611
dc.identifierhttp://arxiv.org/abs/cond-mat/0610611
dc.identifierActa Physica 3 (2007) 17
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/170939
dc.subjectStrongly Correlated Electrons
dc.titleMagnetic properties and the electronic structure of LiCoO_2
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