Entropy and dynamic properties of water below the homogeneous nucleation temperature
| dc.creator | Starr, Francis W. | |
| dc.creator | Angell, C. Austen | |
| dc.creator | Speedy, Robin J. | |
| dc.creator | Stanley, H. Eugene | |
| dc.date | 1999-03-31 | |
| dc.date | 1999-09-10 | |
| dc.date.accessioned | 2026-07-07T03:13:09Z | |
| dc.date.available | 2026-07-07T03:13:09Z | |
| dc.description | Controversy exists regarding the possible existence of a transition between the liquid and glassy states of water. Here we use experimental measurements of the entropy, specific heat, and enthalpy of both liquid and glassy water to construct thermodynamically-plausible forms of the entropy in the difficult-to-probe region between 150 K and 236 K. We assume there is no discontinuity in the entropy of the liquid in this temperature range, and use the Adam-Gibbs theory -- which relates configurational entropy to dynamic behavior -- to predict that dynamic quantities such as the diffusion constant and the viscosity pass through an inflection where the liquid behavior changes from that of an extremely ``fragile'' liquid to that of a ``strong'' liquid. | |
| dc.identifier | https://arxiv.org/abs/cond-mat/9903451 | |
| dc.identifier | http://arxiv.org/abs/cond-mat/9903451 | |
| dc.identifier.uri | http://salesiana.dossiersoluciones.com/handle/123456789/29186 | |
| dc.subject | Condensed Matter | |
| dc.title | Entropy and dynamic properties of water below the homogeneous nucleation temperature | |
| dc.type | text |