Dynamical Matrices and Interatomic-Force Constants from Wave-Commensurate Supercells

dc.creatorLawler, Hadley M.
dc.creatorChang, Eric K.
dc.creatorShirley, Eric L.
dc.date2004-07-08
dc.date2004-07-13
dc.date.accessioned2026-07-07T02:59:07Z
dc.date.available2026-07-07T02:59:07Z
dc.descriptionWe apply standard, first-principles calculations to a complete treatment of lattice dynamics in the harmonic approximation. The algorithm makes use of the straightforward ``frozen-phonon'' approach to the calculation of vibrational spectra and addresses some limitations of the method. Our prescription's validity is independent of crystal structure. It treats polar crystals in a general way, and it incorporates interatomic-force constants reaching beyond the supercell that is considered. For a range of materials, phonon dispersion exhibits the close agreement with experiment that is now characteristic of first-principles schemes. Results for graphite, Si and GaAs are presented.
dc.description18 pages, 3 figures. v2 includes updated references
dc.identifierhttps://arxiv.org/abs/cond-mat/0407221
dc.identifierhttp://arxiv.org/abs/cond-mat/0407221
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/24384
dc.subjectMaterials Science
dc.titleDynamical Matrices and Interatomic-Force Constants from Wave-Commensurate Supercells
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