Chiral Symmetry Breaking in Bent-Core Liquid Crystals
| dc.creator | Longa, Lech | |
| dc.creator | Pająk, Grzegorz | |
| dc.creator | Wydro, Thomas | |
| dc.date | 2009-02-04 | |
| dc.date.accessioned | 2026-07-07T13:09:46Z | |
| dc.date.available | 2026-07-07T13:09:46Z | |
| dc.description | By molecular modeling we demonstrate that the nematic long-range order discovered in bent-core liquid crystal systems should reveal further spatially homogeneous phases. Two of them are identified as a tetrahedratic nematic ($N_T$) phase with $D_{2d}$ symmetry and a chiral tetrahedratic nematic ($N_T^*$) phase with $D_2$ symmetry. These new phases were found for a lattice model with quadrupolar and octupolar anisotropic interactions using Mean Field theory and Monte Carlo simulations. The phase diagrams exhibit tetrahedratic ($T$), $N_T$ and $N_T^*$ phases, in addition to ordinary isotropic ($I$), uniaxial nematic ($N_U$) and biaxial nematic ($N_B$) phases. To our knowledge, this is the first molecular model with spontaneous chiral symmetry breaking in non-layered systems. | |
| dc.description | 12 pages, 4 figures, submitted for publication | |
| dc.identifier | https://arxiv.org/abs/0902.0671 | |
| dc.identifier | http://arxiv.org/abs/0902.0671 | |
| dc.identifier | Phys. Rev. E 79, 040701 (2009) | |
| dc.identifier | doi:10.1103/PhysRevE.79.040701 | |
| dc.identifier.uri | http://salesiana.dossiersoluciones.com/handle/123456789/228848 | |
| dc.subject | Soft Condensed Matter | |
| dc.title | Chiral Symmetry Breaking in Bent-Core Liquid Crystals | |
| dc.type | text |