Electron transfer theory revisit: Quantum solvation effect

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dc.creatorHan, Ping
dc.creatorXu, Rui-Xue
dc.creatorCui, Ping
dc.creatorMo, Yan
dc.creatorHe, Guozhong
dc.creatorYan, YiJing
dc.date2006-06-06
dc.date.accessioned2026-07-07T07:18:40Z
dc.date.available2026-07-07T07:18:40Z
dc.descriptionThe effect of solvation on the electron transfer (ET) rate processes is investigated on the basis of the exact theory constructed in J. Phys. Chem. B Vol. 110, (2006); quant-ph/0604071. The nature of solvation is studied in a close relation with the mechanism of ET processes. The resulting Kramers' turnover and Marcus' inversion characteristics are analyzed accordingly. The classical picture of solvation is found to be invalid when the solvent longitudinal relaxation time is short compared with the inverse temperature.
dc.description5 pages, 3 figures. J. Theo. & Comput. Chem., accepted
dc.identifierhttps://arxiv.org/abs/physics/0606058
dc.identifierhttp://arxiv.org/abs/physics/0606058
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/114386
dc.subjectChemical Physics
dc.titleElectron transfer theory revisit: Quantum solvation effect
dc.typetext

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