Pressure-induced order-disorder phase transition in superconducting CaC6
| dc.creator | Gauzzi, A. | |
| dc.creator | Bendiab, N. | |
| dc.creator | d'Astuto, M. | |
| dc.creator | Canny, B. | |
| dc.creator | Calandra, M. | |
| dc.creator | Mauri, F. | |
| dc.creator | Loupias, G. | |
| dc.creator | Emery, N. | |
| dc.creator | Herold, C. | |
| dc.creator | Lagrange, P. | |
| dc.creator | Hanfland, M. | |
| dc.creator | Mezouar, M. | |
| dc.date | 2008-02-22 | |
| dc.date.accessioned | 2026-07-07T09:22:45Z | |
| dc.date.available | 2026-07-07T09:22:45Z | |
| dc.description | By means of synchrotron X-ray diffraction, we studied the effect of high pressure, P, up to 13 GPa on the room temperature crystal structure of superconducting CaC6. In this P range, no change of the pristine space group symmetry, \textit{R\=3m}, is found. However, at 9 GPa, i.e. close to the critical value at which a large T_c reduction was reported recently, we observed a compressibility jump concomitant to a large broadening of Bragg peaks. The reversibility of both effects upon depressurization and symmetry arguments give evidence of an order-disorder phase transition of second order, presumably associated with the Ca sublattice, which provides a full account for the above Tc reduction. | |
| dc.description | 9 pages, 3 figures | |
| dc.identifier | https://arxiv.org/abs/0802.3273 | |
| dc.identifier | http://arxiv.org/abs/0802.3273 | |
| dc.identifier.uri | http://salesiana.dossiersoluciones.com/handle/123456789/155486 | |
| dc.subject | Superconductivity | |
| dc.subject | Materials Science | |
| dc.title | Pressure-induced order-disorder phase transition in superconducting CaC6 | |
| dc.type | text |