Metastability in Markov processes

dc.creatorLarralde, Hernan
dc.creatorLeyvraz, Francois
dc.creatorSanders, David P.
dc.date2006-08-19
dc.date.accessioned2026-07-07T07:19:44Z
dc.date.available2026-07-07T07:19:44Z
dc.descriptionWe present a formalism to describe slowly decaying systems in the context of finite Markov chains obeying detailed balance. We show that phase space can be partitioned into approximately decoupled regions, in which one may introduce restricted Markov chains which are close to the original process but do not leave these regions. Within this context, we identify the conditions under which the decaying system can be considered to be in a metastable state. Furthermore, we show that such metastable states can be described in thermodynamic terms and define their free energy. This is accomplished showing that the probability distribution describing the metastable state is indeed proportional to the equilibrium distribution, as is commonly assumed. We test the formalism numerically in the case of the two-dimensional kinetic Ising model, using the Wang--Landau algorithm to show this proportionality explicitly, and confirm that the proportionality constant is as derived in the theory. Finally, we extend the formalism to situations in which a system can have several metastable states.
dc.description30 pages, 5 figures; version with one higher quality figure available at http://www.fis.unam.mx/~dsanders/
dc.identifierhttps://arxiv.org/abs/cond-mat/0608439
dc.identifierhttp://arxiv.org/abs/cond-mat/0608439
dc.identifierJ. Stat. Mech. (2006) P08013
dc.identifierdoi:10.1088/1742-5468/2006/08/P08013
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/114737
dc.subjectStatistical Mechanics
dc.subjectSoft Condensed Matter
dc.titleMetastability in Markov processes
dc.typetext

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