Current-induced nonequilibrium vibrations in single-molecule devices

dc.creatorKoch, Jens
dc.creatorSemmelhack, Matthias
dc.creatorvon Oppen, Felix
dc.creatorNitzan, Abraham
dc.date2005-04-05
dc.date2006-04-16
dc.date.accessioned2026-07-07T06:37:39Z
dc.date.available2026-07-07T06:37:39Z
dc.descriptionFinite-bias electron transport through single molecules generally induces nonequilibrium molecular vibrations (phonons). By a mapping to a Fokker-Planck equation, we obtain analytical scaling forms for the nonequilibrium phonon distribution in the limit of weak electron-phonon coupling $λ$ within a minimal model. Remarkably, the width of the phonon distribution diverges as $\simλ^{-α}$ when the coupling decreases, with voltage-dependent, non-integer exponents $α$. This implies a breakdown of perturbation theory in the electron-phonon coupling for fully developed nonequilibrium. We also discuss possible experimental implications of this result such as current-induced dissociation of molecules.
dc.description7 pages, 4 figures; revised and extended version published in Phys. Rev. B
dc.identifierhttps://arxiv.org/abs/cond-mat/0504095
dc.identifierhttp://arxiv.org/abs/cond-mat/0504095
dc.identifierPhys. Rev. B 73, 155306 (2006)
dc.identifierdoi:10.1103/PhysRevB.73.155306
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/100467
dc.subjectMesoscale and Nanoscale Physics
dc.titleCurrent-induced nonequilibrium vibrations in single-molecule devices
dc.typetext

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