Random-Site Cation Ordering and Dielectric Properties of PbMg1/3Nb2/3o3-PbSc1/2Nb1/2o3

Simple item page
dc.creatorRaevski, I. P.
dc.creatorProsandeev, S. A.
dc.creatorEmelyanov, S. M.
dc.creatorSavenko, F. I.
dc.creatorZakharchenko, I. N.
dc.creatorBunina, O. A.
dc.creatorBogatin, A. S.
dc.creatorRaevskaya, S. I.
dc.creatorGagarina, E. S.
dc.creatorSahkar, E. V.
dc.creatorJastrabik, L.
dc.date2003-02-25
dc.date.accessioned2026-07-07T02:49:47Z
dc.date.available2026-07-07T02:49:47Z
dc.description(1-x)PbMg1/3Nb2/3O3-(x)PbSc1/2Nb1/2O3 (PMN-PSN) solid solution crystals have been grown by the flux method in the whole concentration range. X-ray supercell reflections due to B-cation ordering were observed for as-grown crystals from the 0.1 < x < 0.65 compositional range. Though the ordered domains are rather large (~50 nm) the relaxor-like dielectric behavior is observed for compositions with x < 0.6. The diffusion of the dielectric permittivity maximum in as-grown crystals is the lowest at x = 0.6 and increases towards the end members of solid solution. Such behavior is explained within a Bragg-Williams approach by employing the random layer model. At x ~ 0.6 the excitation energy determined from the Vogel-Fulcher relation exhibits a jump which we regard to changing the kind of the polar regions from PbMg1/3Nb2/3O3 to PbSc1/2Nb1/2O3 related type.
dc.description10 pages, Integrated Ferroelectrics 2003
dc.identifierhttps://arxiv.org/abs/cond-mat/0302520
dc.identifierhttp://arxiv.org/abs/cond-mat/0302520
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/20936
dc.subjectMaterials Science
dc.titleRandom-Site Cation Ordering and Dielectric Properties of PbMg1/3Nb2/3o3-PbSc1/2Nb1/2o3
dc.typetext

Files

Collections

arXiv