Structure and Magnetism of the mono-layer hydrate Na0.3NiO2 0.7H2O
Abstract
Description
The mono-layer hydrate (Ni-MLH) Na0.3NiO2 0.7H2O was synthesized with an average Ni valence close to one in the bi-layer hydrate (Ni-BLH) Na0.3NiO2 1.3H2O. A weak unsaturated ferromagnetism and divergence of the magnetic susceptibilities of field and zero-field cooled samples of both Ni-MLH and Ni-BLH are observed. However, as a result of the increased 3-dimensional electronic and magnetic character present in Ni-MLH a frequency dependence of the AC magnetic susceptibility indicative of the spin glass-like behavior as seen in Ni-BLH was no longer observed in Ni-MLH.
17 pages 6 figures to be published in Solid State Communications
17 pages 6 figures to be published in Solid State Communications