Raman scattering from phonons and magnons in RFe3)BO3)4

Fausti, Daniele; Nugroho, Agung; van Loosdrecht, Paul H. M.; Klimin, Sergei A.; Popova, Marina N.; Bezmaternykh, Leonard N.

Raman scattering from phonons and magnons in RFe3)BO3)4

Authors

Fausti, Daniele

Nugroho, Agung

van Loosdrecht, Paul H. M.

Klimin, Sergei A.

Popova, Marina N.

Bezmaternykh, Leonard N.

Description

Inelastic light scattering spectra of several members of the RFe3(BO3)4 family reveal a cascade of phase transitions as a function of temperature, starting with a structural, weakly first order, phase transition followed by two magnetic phase transitions. Those consist of the ordering of the Fe-spin sublattice revealed by all the compound, and a subsequent spin-reorientational transition for GdFe3(BO3)4. The Raman data evidence a strong coupling between the lattice and magnetic degrees of freedom in these borates. The Fe-sublattice ordering leads to a strong suppression of the low energy magnetic scattering, and a multiple peaked two-magnon scattering continuum is observed. Evidence for short-range correlations is found in the `paramagnetic' phase by the observation of a broad magnetic continuum in the Raman data, which persists up to surprisingly high temperatures.
17 pages, 13 figures