Accurate measurement of ^{13}C - ^{15}N distances with solid-state NMR
Abstract
Description
Solid-state NMR technique for measureing distances between hetero-nuclei in static powder samples is described. It is based on a two-dimensional single-echo scheme enhanced with adiabatic cross-polarization. As an example, the results for intra-molecular distances in $α$-crystalline form of glycine are presented. The measured NMR distances ^13 C(2) - ^15 N and ^13 C(1) - ^15 N are 1.496 $\pm$ 0.002 Åand 2.50 $\pm$ 0.02 Å, respectively.
12 pages
12 pages