Constrained equilibrium as a tool for characterization of deformable porous media

dc.creatorVakarin, E. V.
dc.creatorDuda, Yurko
dc.creatorBadiali, J. P.
dc.date2006-09-20
dc.date.accessioned2026-07-07T07:23:37Z
dc.date.available2026-07-07T07:23:37Z
dc.descriptionA new method for characterizing the deformable porous materials with non-critical adsorption probes is proposed. The mechanism is based on a driving the adsorbate through a sequence of constrained equilibrium states with the insertion isotherms forming a pseudo-critical point or a van der Waals-type loop. In the framework of a perturbation theory and Monte Carlo simulations we have found a link between the loop parameters and the host morphology. This allows one to characterize porous matrices through analyzing a shift of the pseudo-critical point and a shape of the pseudo-spinodals.
dc.identifierhttps://arxiv.org/abs/cond-mat/0609505
dc.identifierhttp://arxiv.org/abs/cond-mat/0609505
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/116050
dc.subjectStatistical Mechanics
dc.titleConstrained equilibrium as a tool for characterization of deformable porous media
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