Alkanethiol-Based Single-Molecule Transistors

dc.creatorMa, Chun-Lan
dc.creatorNghiem, Diu
dc.creatorChen, Yu-Chang
dc.date2008-04-23
dc.date2008-12-02
dc.date.accessioned2026-07-07T12:59:57Z
dc.date.available2026-07-07T12:59:57Z
dc.descriptionThe transport properties of unsubstituted and amino-substituted butanethiol molecules sandwiched between Au electrodes are investigated by using first-principles approaches. New states are observed around the Fermi levels when -NH2 is substituted for -H in the bridging butanethiol. The amino-substituted states lead to a sharp increase of the current which is credited to the resonant tunneling in the junction. We observe a novel conductance peak at VSD = 0.1 V and negative differential resistance (NDR) in a certain range of source-drain bias. In addition to the I-VSD characteristics, we also investigate the current as a function of gate voltage (I-VG) and find that, for a fixed source-drain bias (VSD = 0.01 V), the gate voltage can modulate the conductance by up to 30 times in the amino-substituted butanethiol junction. These I-VG characteristics suggest that the amino-substituted butanethiol molecular junction may be a promising candidate for field-effect transistors.
dc.description4 pages
dc.identifierhttps://arxiv.org/abs/0804.3637
dc.identifierhttp://arxiv.org/abs/0804.3637
dc.identifierApplied Physics Letters, 93 222111 (2008)
dc.identifierdoi:10.1063/1.3043438
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/225732
dc.subjectMesoscale and Nanoscale Physics
dc.subjectMaterials Science
dc.titleAlkanethiol-Based Single-Molecule Transistors
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