Density scaling of the diffusion coefficient at various pressures in viscous liquids

dc.creatorPapathanassiou, A. N.
dc.date2009-03-06
dc.date2009-03-22
dc.date.accessioned2026-07-07T12:58:05Z
dc.date.available2026-07-07T12:58:05Z
dc.descriptionFundamental thermodynamics and an earlier elastic solid-state point defect model [P. Varotsos and K. Alexopoulos, Phys. Rev B 15, 4111 (1977); 18, 2683 (1978)] are employed to formulate an analytical second-order polynomial function describing the density scaling of the diffusion coefficient in viscous liquids. The function parameters are merely determined by the scaling exponent, which is directly connected with the Gruneisen constant. Density scaling diffusion coefficient isotherms obtained at different pressures collapse on a unique master curve, in agreement with recent computer simulation results of Lennard-Jones viscous liquids, [D. Coslovich and C.M. Roland, J. Phys. Chem. B 112, 1329 (2008)].
dc.descriptionAccepted for publication in Phys. Rev. E (2009) Minor typos corrected in the 2nd version
dc.identifierhttps://arxiv.org/abs/0903.1307
dc.identifierhttp://arxiv.org/abs/0903.1307
dc.identifierPhys. Rev. E 79, 032501 (2009)
dc.identifierdoi:10.1103/PhysRevE.79.032501
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/225125
dc.subjectSoft Condensed Matter
dc.subjectStatistical Mechanics
dc.titleDensity scaling of the diffusion coefficient at various pressures in viscous liquids
dc.typetext

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