Model of Electrochemical "Double Layer" Using the Phase Field Method

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dc.creatorGuyer, J. E.
dc.creatorBoettinger, W. J.
dc.creatorWarren, J. A.
dc.creatorMcFadden, G. B.
dc.date2002-03-20
dc.date.accessioned2026-07-07T02:44:45Z
dc.date.available2026-07-07T02:44:45Z
dc.descriptionWe present the first application of phase field modeling to electrochemistry. A free energy functional that includes the electrostatic effect of charged particles leads to rich interactions between concentration, electrostatic potential, and phase stability. The present model, explored for the equilibrium planar interface, properly predicts the charge separation associated with the equilibrium double layer at the electrochemical interface and its extent in the electrolyte as a function of electrolyte concentration, as well as the form expected of surface energy vs. potential ("electrocapillary") curves.
dc.description14 pages, 10 figures
dc.identifierhttps://arxiv.org/abs/cond-mat/0203420
dc.identifierhttp://arxiv.org/abs/cond-mat/0203420
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/19054
dc.subjectMaterials Science
dc.titleModel of Electrochemical "Double Layer" Using the Phase Field Method
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