Electrostatics of Phase Boundaries in Coulomb systems

dc.creatorIosilevskiy, Igor
dc.creatorChigvintsev, Alexander
dc.date2009-01-16
dc.date.accessioned2026-07-07T12:30:58Z
dc.date.available2026-07-07T12:30:58Z
dc.descriptionAny interface boundary in an equilibrium system of Coulomb particles is accompanied by the existence of a finite difference in the average electrostatic potential through this boundary. The discussed interface potential drop is a thermodynamic quantity. It depends on temperature only and does not depend on surface properties. The zero-temperature limit of this drop (along the coexistence curve) is an individual substance coefficient. At high temperature the drop tends to zero at critical point of gasliquid phase transition. A special critical exponent can be defined to describe this behavior. Study of the interface potential drop is illuminative in simplified Coulomb models: i.e. for melting and evaporation in variants of One Component Plasma model (OCP), or for model of Charged Hard/Soft Spheres (CHS/CSS) etc. In all these cases properties of the potential drop can be easily calculated by the DNS methods (direct numerical simulation) when the two-phase coexistence in Coulomb system is really simulated. Electrostatics of phase boundaries in real systems could be elucidated in analytical calculation of two-phase coexistence via finite-temperature DFT approach (density functional theory).
dc.description4 pages, 1 figure, Proceedings of 30th EPS Conference on Contr. Fusion and Plasma Phys., St. Petersburg, 7-11 July 2003
dc.identifierhttps://arxiv.org/abs/0901.2389
dc.identifierhttp://arxiv.org/abs/0901.2389
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/216300
dc.subjectPlasma Physics
dc.titleElectrostatics of Phase Boundaries in Coulomb systems
dc.typetext

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