Accurate long-range coefficients for two excited like isotope He atoms: He($2 ^1P$)--He($2 ^1P$), He($2 ^1P$)--He($2 ^3P$), and He($2 ^3P$)--He($2 ^3P$)

dc.creatorZhang, J. -Y.
dc.creatorYan, Z. -C.
dc.creatorVrinceanu, D.
dc.creatorBabb, J. F.
dc.creatorSadeghpour, H. R.
dc.date2007-05-11
dc.date.accessioned2026-07-07T08:21:15Z
dc.date.available2026-07-07T08:21:15Z
dc.descriptionA general formalism is used to express the long-range potential energies in inverse powers of the separation distance between two like atomic or molecular systems with $P$ symmetries. The long-range molecular interaction coefficients are calculated for the molecular symmetries $Δ$, $Π$, and $Σ$, arising from the following interactions: He($2 ^1P$)--He($2 ^1P$), He($2 ^1P$)--He($2 ^3P$), and He($2 ^3P$)--He($2 ^3P$). The electric quadrupole-quadrupole term, $C_{5}$, the van der Waals (dispersion) term $C_{6}$, and higher-order terms, $C_{8}$, and $C_{10}$, are calculated \textit{ab initio} using accurate variational wave functions in Hylleraas coordinates with finite nuclear mass effects. A comparison is made with previously published results where available.
dc.identifierhttps://arxiv.org/abs/0705.1604
dc.identifierhttp://arxiv.org/abs/0705.1604
dc.identifierPhys. Rev. A 76, 012723 (2007)
dc.identifierdoi:10.1103/PhysRevA.76.012723
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/135301
dc.subjectAtomic Physics
dc.subjectComputational Physics
dc.titleAccurate long-range coefficients for two excited like isotope He atoms: He($2 ^1P$)--He($2 ^1P$), He($2 ^1P$)--He($2 ^3P$), and He($2 ^3P$)--He($2 ^3P$)
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