Direct charge ejection for chemical electric generation
| dc.creator | Zuppero, Anthony | |
| dc.creator | Dolan, Thomas J. | |
| dc.date | 2009-04-29 | |
| dc.date.accessioned | 2026-07-07T13:09:53Z | |
| dc.date.available | 2026-07-07T13:09:53Z | |
| dc.description | A particular type of surface chemical reaction resulted in direct charge ejection. Several different experimental observations strongly support the hypothesis that nearly all of the molecular kinetic energy of a highly excited vibrating molecule was transferred to the kinetic energy of a single electron in a conducting lattice, leaving the molecule in nearly its ground state. This kinetic energy transfer represents the counterpart to the potential energy transfer in a battery, where electrochemical potential energy of reactants is transferred to the electrical potential energy of a separated charge. Here chemical reaction energy is transferred directly to the kinetic energy of a charge instead of to the potential energy of a charge. These observations indicate a breakdown of the Born Oppenheimer approximation. | |
| dc.description | 12 pages, 6 figures | |
| dc.identifier | https://arxiv.org/abs/0904.4522 | |
| dc.identifier | http://arxiv.org/abs/0904.4522 | |
| dc.identifier.uri | http://salesiana.dossiersoluciones.com/handle/123456789/228888 | |
| dc.subject | Chemical Physics | |
| dc.title | Direct charge ejection for chemical electric generation | |
| dc.type | text |