Direct charge ejection for chemical electric generation

dc.creatorZuppero, Anthony
dc.creatorDolan, Thomas J.
dc.date2009-04-29
dc.date.accessioned2026-07-07T13:09:53Z
dc.date.available2026-07-07T13:09:53Z
dc.descriptionA particular type of surface chemical reaction resulted in direct charge ejection. Several different experimental observations strongly support the hypothesis that nearly all of the molecular kinetic energy of a highly excited vibrating molecule was transferred to the kinetic energy of a single electron in a conducting lattice, leaving the molecule in nearly its ground state. This kinetic energy transfer represents the counterpart to the potential energy transfer in a battery, where electrochemical potential energy of reactants is transferred to the electrical potential energy of a separated charge. Here chemical reaction energy is transferred directly to the kinetic energy of a charge instead of to the potential energy of a charge. These observations indicate a breakdown of the Born Oppenheimer approximation.
dc.description12 pages, 6 figures
dc.identifierhttps://arxiv.org/abs/0904.4522
dc.identifierhttp://arxiv.org/abs/0904.4522
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/228888
dc.subjectChemical Physics
dc.titleDirect charge ejection for chemical electric generation
dc.typetext

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