HfO$_2$: a new direction for intrinsic defect driven ferromagnetism

dc.creatorPemmaraju, Chaitanya Das
dc.creatorSanvito, S.
dc.date2005-02-09
dc.date.accessioned2026-07-07T03:03:41Z
dc.date.available2026-07-07T03:03:41Z
dc.descriptionIn view of the recent experimental reports of unexpected ferromagnetism in HfO$_{2}$ thin films, we carried out first principles investigations looking for magnetic order possibly brought about by the presence of small concentrations of intrinsic point defects. {\it Ab initio} electronic structure calculations using density functional theory (DFT) show that isolated cation vacancy sites in HfO$_{2}$ lead to the formation of high spin defect states. Furthermore these appear to be ferromagnetically coupled with a rather short range magnetic interaction, resulting in a ferromagnetic ground state for the whole system. More interestingly, the occurrence of these high spin states and ferromagnetism is in the low symmetry monoclinic phase of HfO$_{2}$. This is radically different from other systems previously known to exhibit point defect ferromagnetism, warranting a closer look at the phenomenon.
dc.description4 pages, 6 figures
dc.identifierhttps://arxiv.org/abs/cond-mat/0502246
dc.identifierhttp://arxiv.org/abs/cond-mat/0502246
dc.identifier.urihttp://salesiana.dossiersoluciones.com/handle/123456789/25843
dc.subjectMaterials Science
dc.subjectStrongly Correlated Electrons
dc.titleHfO$_2$: a new direction for intrinsic defect driven ferromagnetism
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