2026-07-072026-07-07http://salesiana.dossiersoluciones.com/handle/123456789/127411By means of low-temperature expansions (LTEs), the nucleation free energy and the precipitate interface free energy are expressed as functions of the solubility limit for alloys which lead to the precipitation of a stoichiometric L12 compound such as Al-Sc or Al-Zr alloys. Classical nucleation theory is then used to obtain a simple expression of the nucleation rate whose validity is demonstrated by a comparison with atomic simulations. LTEs also explain why simple mean-field approximation like the Bragg-Williams approximation fails to predict correct nucleation rates in such an ordering alloy.Materials Sciencetext